If you have 65.54.190.64/26, it means that it is the network address. You can use IPs from range 65.54.190.65-65.54.190.126, have netmask 255.255.255.192 and 65.54.190.127 is broadcast address.
These are the subnets of your network
65.54.190.0(broadcast ID) 65.54.190.1 - 62( IP Range) 65.54.190.63(Network ID)
255.255.255.192 will your subnet mask
Meaning in this network your have only 62 IPs to use
65.54.190.64 and the rests are in different network
65.54.190.0(broadcast ID) 65.54.190.1 - 62(IP Range) 65.54.190.63(Network ID)
meaning you have 62 available IPs in this network and the subnet mask is 255.255.255.192
65.54.190.64 and the rest are another network
To be clear here - it MS say that email may come from the 65.54.190.64/26 block then you should assume that it means from any of the IPs from .64 to .127 . The restriction on the use of .64 and .127 only occurs if the block is applied to a broadcast network such as Ethernet. In other situations all the addresses may be used.