This is an IT problem, not a Network issue. This should be enforced on each account or PC with domain services or group policy; it would be unenforceable otherwise.
set Google dns for all (static dns on pc, dhcp assigned,..)
set OpenDns dns on MT
create a address-list for privileged/bypassed dns users
create a firewall dns redirect for all but exclude the privileged address-list
Normal user dns request is redirected to MT (asked to Opendns), privileged user will bypass dns trick (Google).
Finally ..enable/disable the redirect rule on schedule.
(Beware ..this doesn’t work for cached dns; when schedule enable redirect rule, your users can still use the (eventual) previously cached dns response ..untill the ttl die. I mainly use this schema when dns filters are permanent and it works well)