If client devices resolve both IPv4 and IPv6 addresses for a target site they will use IPv6 in preference to IPv4 to connect. AFAIK Android and iOS implement ‘Happy Eyeballs’ for fast fallback to IPv4, and some PC programs do but I don’t believe Windows itself does.
Static IPv6 NXDOMAIN DNS entries should work, but trying to find all of the entries required for sites using content delivery networks will be next to impossible.